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Sodium methylate and then cyclopentadiene are added, and ferrocene ultimately precipitates out of the solution.
Phenyl-substituted cyclopentadienes are proved to form phenylated pyrylium cations in the presence of silver perchlorate by insertion of an oxygen atom into the cyclopentadiene-ring.
The cyclopentadienes are prepared by reaction with hydrocarbylating agents or alcohols.
Nucleophiles can be added, leading to coordinated cyclopentadienes , which may be liberated by oxidation and used in further synthesis.
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